Is it possible to enable and use multiple MFA solutions. For example, is it possible to select both DUO and Azure MFA option in ADFS settings shown below and create a rule/policy that directs some group/users to use Azure MFA and another to use DUO?
Configure 2 MFA Additional authentication methods?
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Yes this is possible in AD FS from Windows Server 2019 onwards as per https://learn.microsoft.com/en-us/windows-server/identity/ad-fs/overview/whats-new-active-directory-federation-services-windows-server#authenticationpolicy-capabilities
See https://learn.microsoft.com/en-us/answers/questions/18531/adfs-2019-multiple-mfa-provider-selection-on-rp.html for claims rules examples.