I try to decode html entities like & which are inside the products description and should be decoded for Feedexport.
As the entities are already inside of the description the |raw filter will not work.
It seems that |html_entity_decode is not available in Shopware 6 Twig?
Are there any other options to decode entities like & in twig?
Other than replacing every possible html entity with the decoded value, no.
You could create a small plugin that adds a twig filter for decoding html entities.
Then
product.description|html_entity_decodeetc should work.