Why does exactly -LLONG_MIN lead to undefined behavior?
C11, 6.5.3.3p3:
The result of the unary - operator is the negative of its (promoted) operand. The integer promotions are performed on the operand, and the result has the promoted type.
Here we see that the C standard doesn't require that unary - operator to be implemented, for example, using bitwise-not followed by adding 1, where "adding 1" may lead to undefined behavior.
How to deduce from the quoted text that -LLONG_MIN leads to undefined behavior?
It is not possible to deduce it from the quoted text. You also need this text https://port70.net/~nsz/c/c11/n1570.html#6.5p5 :
On implementations in which the mathematical result of
-LLONG_MINis not representable inlong longtype, this rule is triggered and behavior is undefined.